GCSE · Chemistry · Edexcel · Spec 1CH0

Development of the atomic model (Dalton onwards)

Rutherford fired particles at gold, expecting every one to sail straight through. Most did. A few bounced straight back. What does that do to the atom?

Chemistry · Atomic structure

Five models, five dates

Drag each tag to the year you think it happened, then check. Which ideas arrived close together, and which had to wait?

Predict, then check

Picture Thomson's plum pudding: a ball of positive charge with negative electrons embedded in it. Now Rutherford's group fires positive alpha particles at very thin gold foil, with a detector tracking where each one ends up.

Using the plum pudding model, what did Rutherford expect to happen to the alpha particles?

Relationship matrix

Tap any cell to reveal it. Tap a column header to read one property down every item.

What it showedQuick hook
Most went straight through
A few rebounded straight back
Some were deflected at an angle

Each cell hides a short answer and the reason behind it. Predict before you tap.

Plum pudding vs nuclear

Plum pudding modelvsNuclear model

Lead with what changed. Then notice what did not.

Focus

Where the positive charge is

Plum pudding model

A ball of positive charge, with no nucleus

Nuclear model

A small positive nucleus in the centre

The insight

The big change is the nucleus: a small positive centre instead of a ball of positive charge.

What the electrons do

Plum pudding model

Embedded in the ball, stuck in position and not moving around

Nuclear model

A cloud of electrons orbiting the nucleus, moving around it

Charges present

Plum pudding model

Positive and negative

Nuclear model

Positive and negative

Protons

Plum pudding model

None

Nuclear model

None

Chemistry · Atomic structure

Whose idea was it?

Which scientist does each idea belong to?

Still to sort

Dalton (0)

1803

Thomson (0)

1897

Rutherford (0)

Gold foil experiment, 1909

Bohr (0)

1913

Chadwick (0)

1932

8 of 8 still to sort.

WHAT YOU'VE LEARNED

A quick recap of today's lesson.

Five scientists, five models, and one experiment that made everyone rethink the atom.

What you need to know

  • Atomic models have changed over time. Dalton (1803) said atoms are tiny, hard, solid spheres that cannot be divided.
  • Thomson (1897) found atoms are not solid spheres. They contain smaller, negatively charged particles called electrons.
  • His plum pudding model: electrons embedded in a ball of positive charge, stuck in position and not moving around.
  • Have a goYour mate says Thomson's electrons whizz around the plum pudding like tiny planets. What do you tell them?

    In the plum pudding model the electrons are stuck in position and do not move around.

    The electrons are embedded in the ball of positive charge, so they stay fixed in place.

  • In 1909, Rutherford and his research group fired positive alpha particles at very thin gold foil, with a detector tracking their paths.
  • Rutherford expected every alpha particle to go straight through. Most did, a few rebounded straight back, and some were deflected.
  • Have a goRutherford expected every alpha particle to go straight through. Which results did he not expect?

    A few rebounding straight back, and some being deflected at an angle.

    Only 'most went straight through' fits his expectation, and even that fell short of 'every one'.

  • Those results proved the plum pudding model wrong. Most going straight through means the atom is mostly empty space.
  • A few rebounding means a tiny, dense nucleus at the centre. Deflection means that nucleus is positively charged.
  • The nuclear model: a small positive nucleus surrounded by a cloud of orbiting electrons, in an atom that is mostly empty space.
  • Bohr (1913) adapted it: electrons orbit at fixed distances, in energy levels or shells. His calculations agreed with experiments.
  • Rutherford showed the nucleus divides into positive protons. Chadwick (1932) found the neutron: similar mass, but no charge.
  • Have a goCompare the neutron with the proton: what is the same, and what is different?

    Similar mass. The proton is positive; the neutron has no charge.

    Chadwick's particle matches the proton for mass, but it carries no charge, unlike the positive proton.

The big picture

The model of the atom was rebuilt several times: Dalton's solid spheres, Thomson's plum pudding, Rutherford's nucleus, Bohr's shells and Chadwick's neutron. Each change followed new evidence, and the gold foil experiment was the turning point.

Key points

1Dalton (1803): atoms are tiny, hard, solid spheres that cannot be divided, and each element is made of identical atoms.
2Thomson (1897) showed atoms contain negatively charged electrons: the plum pudding model, with electrons embedded in a ball of positive charge.
3In the gold foil experiment most alpha particles went straight through, a few rebounded and some were deflected. This proved the plum pudding model incorrect.
4The nuclear model has a small positive nucleus with a cloud of orbiting electrons, and the atom is mostly empty space.
5Bohr (1913) put the electrons at fixed distances in energy levels or shells. Rutherford showed the nucleus contains protons, and Chadwick (1932) found the neutron.

Worked example

Problem

Rutherford's nuclear model has negative electrons orbiting a positive nucleus. Explain why scientists were puzzled by this, and say what Bohr did in 1913.

⚠ Watch out

Thinking the atom was worked out once and never changed. Every model was replaced or refined when new evidence appeared. Also watch the mix-up between the two big models: plum pudding electrons are stuck in position, nuclear-model electrons move around the nucleus, and neither model had protons yet.

🧠

Memory hook

Ball, Pudding, Nucleus, Shells, Neutron: that is Dalton, Thomson, Rutherford, Bohr, Chadwick, in order. Each name is one step forced by new evidence.

✓

Check yourself

Cover the page. Put the five scientists in order with their dates, say what each one changed, and explain which gold foil result showed there was a tiny, dense nucleus.

Flashcards

(13)
What did Dalton suggest about atoms in 1803?
That atoms are tiny, hard, solid spheres that cannot be divided.
How did Dalton say the atoms of different elements compare?
Each element is made of identical atoms (all carbon atoms are the same), and the atoms of one element differ from the atoms of another element.
What did Thomson show in 1897?
Atoms are not solid spheres. They contain smaller, subatomic, negatively charged particles called electrons.
What is the plum pudding model?
A ball of positive charge with negative electrons embedded in it, stuck in position and not moving around.
How was the gold foil experiment set up in 1909?
Rutherford and his research group fired positive alpha particles at very thin gold foil, surrounded by a detector that could detect the path of the alpha particles.
What did Rutherford expect from the gold foil experiment, and what happened?
He expected all the alpha particles to go straight through. Most did, a few rebounded straight back and some were deflected at an angle.
Most alpha particles went straight through the gold foil. What does that show?
Most of the atom is empty space.
A few alpha particles rebounded straight back. What does that show?
There is a tiny, dense nucleus in the centre of the atom.
Some alpha particles were deflected. What does that show?
The nucleus must be positively charged.
What does the nuclear model look like?
A small positive nucleus in the centre, surrounded by a cloud of orbiting electrons. The atom is mostly empty space.
What did Rutherford show about the nucleus?
It can be subdivided into a whole number of smaller particles, each with the same mass and amount of positive charge. They were named protons.
What did James Chadwick's work in 1932 provide evidence for?
The neutron, a particle in the nucleus with a mass similar to a proton and no charge. It was the last subatomic particle to be discovered.
Why did neither the plum pudding model nor the nuclear model contain protons?
Protons were not suggested until after the nuclear model. Both models did contain positive and negative charges.

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