KS3 · Chemistry

Solubility and saturated solutions

Stir sugar into water, spoon after spoon. Each one vanishes, until one stays at the bottom however hard you stir. Where does the water's limit come from?

Slide the dot along the line to about 75 °C. How much sugar can 100 cm³ of water hold?

3047.56582.5100100200300400500Temperature of the water (°C)Most sugar that dissolves (g)(65, 311.5)

Temperature of the water (°C): 65. Most sugar that dissolves (g): 311.5

Watch out: This is one smooth, illustrative curve for sugar in 100 cm³ of water. The two readings to rely on are about 275 g at 55 °C and about 350 g at 75 °C; treat every other point as 'roughly'.

Why is there a limit?

?

Reason it through

Why can a cup of water only hold so much sugar?

Link 1 of 4

First link · your turn

When sugar dissolves and seems to vanish, what has happened to the sugar?

2
Locked — reveal the link above first
3
Locked — reveal the link above first
4
Locked — reveal the link above first

Faster, or more?

Does it change how fast, how much, or both?

People often say a substance is 'more soluble' when it dissolves quickly. Here the two ideas are kept apart. Tick the set or sets that each change belongs in.

  • A Dissolves faster
  • B Lets more dissolve
  1. Stirring
  2. Smaller pieces (sugar cubes, then granulated, then powdered sugar)
  3. A smaller mass of solute
  4. A larger volume of solvent
  5. A more suitable solvent
  6. A higher temperature of the solvent

Predict, then check

Think about where the limit sits on the curve when the water is cooler.

A sugar solution is saturated at a high temperature. It is left to cool down. What happens to the sugar?

Chemistry · Fair tests

Set up a fair test

You are timing how long 2 g of sugar takes to dissolve in 100 cm³ of water at different temperatures. Sort each quantity, then read why it belongs there.

Still to sort

Independent variable (0)

The thing you change on purpose.

Where the line is: If you choose its values, it is independent. If you read it off an instrument after the test, it is dependent.

Dependent variable (0)

The thing you measure.

Where the line is: It is the result of the test, so it is never set beforehand.

Control variable (0)

Kept the same every time.

Where the line is: A control variable could change the result, so it must not change.

5 of 5 still to sort.

Check the analysis

Find the slip

A student times how long 2 g of sugar takes to dissolve in 100 cm³ of water at different temperatures. At 60 °C she repeats the test three times. Read her write-up and pick the line where it first goes wrong.

A student's write-up (made-up example readings) — which line goes wrong?

WHAT YOU'VE LEARNED

A quick recap of today's lesson.

Keep stirring sugar into water and one spoonful will refuse to disappear. That is the water's limit, and we can draw it.

What you need to know

  • Solubility is about how well a solute dissolves in a solvent to make a solution. Keep two ideas apart: how fast it dissolves, and how much dissolves.
  • At a given temperature there is a limit to how much solute can dissolve. When that limit is reached the solution is saturated: the solvent is full.
  • The solvent, its volume and its temperature decide how much can dissolve. Stirring, smaller pieces and a smaller mass of solute only change how fast.
  • A solubility curve shows the most solute that dissolves in a stated volume of solvent at each temperature, so every point on it is a saturated solution.
  • In a fair test you change one thing, measure one thing and keep the rest the same.

The big picture

At a given temperature there is a limit to how much solute can dissolve in a solvent. A solution that holds that much is saturated. The solvent, its volume and its temperature set the limit, while stirring and smaller pieces only change how fast the solute dissolves. A solubility curve plots the limit against temperature, so every point on the line is a saturated solution, and a fair-test investigation measures how changing one variable affects dissolving.

Key points

1Dissolving: the solute's particles separate and spread out among the solvent's particles, so you can no longer see the solute.
2A saturated solution can hold no more solute at that temperature. The solvent is full.
3More solvent, or hotter solvent, lets more dissolve (hotter works for most substances, not all).
4Cool a saturated solution and solute that no longer fits collects at the bottom or forms crystals.
5On a solubility curve, read up and across for a mass, or across and down for a temperature. With several curves, the highest is the most soluble at that temperature.
6Circle an anomalous result and leave it out of the mean. Continuous data gets a scatter graph and a line of best fit; categories get a bar chart.

Worked example

Problem

A graph shows the solubility curves of three made-up solutes, P, Q and R, in 100 cm³ of water. At 40 °C, curve P reads 60 g, curve Q reads 35 g and curve R reads 20 g. Curve P also passes through 100 g at 60 °C. (a) Which solute is the most soluble at 40 °C, and which is the least? (b) At what temperature does 100 cm³ of water hold exactly 100 g of P?

⚠ Watch out

'Dissolves faster' is not the same as 'dissolves more'. Stirring harder or crushing the sugar gets you to the limit sooner, but it never moves the limit. Only the solvent, its volume and its temperature do that.

🧠

Memory hook

Full means no free hands: once every water particle is busy holding sugar, the extra stays in a pile. More water means more hands; hotter water means more energy to pull sugar particles apart. (Just a picture: particles don't have hands!)

✓

Check yourself

A friend says: 'If I stir for long enough, any amount of sugar will dissolve in my cup of water.' What would you tell them, and which three things really decide how much can dissolve?

Flashcards

(15)
What does 'solubility' describe?
How well a solute can dissolve in a solvent to make a solution. Watch for two meanings: how fast it dissolves, and how much dissolves.
What happens to the solute's particles when it dissolves?
They separate and spread out among the solvent's particles, so you can no longer see the solute.
What is a saturated solution?
One in which no more solute can dissolve at that temperature. The solvent is full.
Name three changes that only make a solute dissolve faster.
Stirring, smaller pieces of solute and a smaller mass of solute.
What decides how much solute can dissolve?
The solvent used, the volume of the solvent and its temperature.
How can you raise the limit, and why does each way work?
More solvent: more solvent particles are available to attract the solute. Hotter solvent: its particles have more energy to overcome the attractions between solute particles. (Hotter works for most substances; for a few, solubility goes down as temperature goes up.)
What happens when a saturated solution cools?
Solute that only dissolved because of the extra energy can't stay dissolved. It collects at the bottom or forms crystals, as in cooled honey or maple syrup.
Two ways to make a saturated solution?
Heat it so that more solute dissolves, or remove some of the solvent (boiling maple sap into syrup, salt pans making sea salt).
What does a solubility curve show?
A line of best fit on a scatter graph: temperature on the x-axis, and on the y-axis the most solute that dissolves in a stated volume of one solvent.
How do you read a solubility curve?
For a mass at a temperature: up from the temperature to the curve, then across. For a temperature at a mass: across from the mass to the curve, then down.
Several solutes are plotted on one graph. How do you find the most soluble?
Pick a temperature. The highest curve there is the most soluble, because it dissolves the greatest mass.
Independent, dependent and control variables?
Independent: what you change. Dependent: what you measure. Control: what you keep the same.
Which apparatus measures mass, volume, temperature and dissolving time?
Balance for mass, measuring cylinder for volume, thermometer for temperature, stopwatch for time.
What is an anomalous result and what do you do with it?
A result that doesn't fit the trend. Circle it and leave it out of the mean and the line of best fit. Mean = sum of results ÷ number of results.
Scatter graph or bar chart?
Continuous data (such as temperature or time) gets a scatter graph with a line of best fit. Discrete data (such as type of sugar) gets a bar chart.

Tap any card to flip it, or use Study as deck to go through them one at a time. In the full lesson these run as a spaced-repetition deck — you rate each card Hard, Good or Easy and the tricky ones keep coming back until they stick.

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