KS3 · Chemistry

Chemical formulae and symbols

H₂O and H₂O₂ look almost the same. One is water; the other is hydrogen peroxide, which is corrosive and harmful. The difference? One small number.

Chemistry · Reading formulae

Element or compound?

Pick a formula, then put it where it belongs. Read the symbols: how many different types of atom can you see?

An element has one type of atom. A compound has two or more types of atom bonded together.

Still to sort

Element (0)

Only one type of atom.

Where the line is: A small number doesn't make a compound. N₂ has two atoms, but they are both nitrogen.

Compound (0)

Two or more types of atom, chemically joined.

Where the line is: Look for a second capital letter — that's a second element.

12 of 12 still to sort.

Every symbol starts with a capital letter, so counting the capitals tells you how many elements a formula contains. The small numbers only say how many atoms — they never add a new type.

Counting the atoms

What the small numbers count
H2OCH4CO2? atoms? atoms? atoms

View: Count it yourself. Showing 2 layers: Formulae, Atoms hidden

View

Explore

tap a part of a formula ↓

How many atoms of each type does each formula show? Decide, then switch to the atoms to check.

Water, methane and carbon dioxide, each drawn beside its atoms.

Chemistry · Formulae as ratios

NaCl: one chlorine for every sodium
012345678910drag the sodium atoms

sodium atoms: 3/10. Sodium atoms 3. Chlorine atoms 3. Sodium : chlorine 3 : 3 = 1 : 1

Sodium atoms3Chlorine atoms3Sodium : chlorine3 : 3 = 1 : 1

Sodium chloride forms a giant structure, so there isn't one small NaCl unit to count. Drag to take more or fewer sodium atoms: the chlorine keeps pace, and the ratio stays 1:1. A real piece of sodium chloride has far more atoms than this — but the same ratio. KBr works the same way: one bromine for every potassium.

Chemistry · Writing formulae

Spot the slip

Write the formulae for (a) a compound of two carbon atoms and six hydrogen atoms, and (b) a compound of one nitrogen atom and one oxygen atom.

A student's answer — which line goes wrong?

Chemistry · Same elements, different substance

Is H₂O₂ just water?

Water is H₂O. Hydrogen peroxide is H₂O₂. Both are made only of hydrogen atoms and oxygen atoms.

Which is closest to what you think right now?
How sure are you?

Same three elements, two substances

EthanolvsEthanoic acid

Ethanol and ethanoic acid are both made of carbon, hydrogen and oxygen. Compare them row by row.

Focus

Formula

Ethanol

C₂H₆O

Ethanoic acid

C₂H₄O₂

The insight

Both start with C₂, but after that the numbers change. Different numbers of atoms, different compound.

Atoms of each element

Ethanol

2 carbon, 6 hydrogen, 1 oxygen

Ethanoic acid

2 carbon, 4 hydrogen, 2 oxygen

Boiling point

Ethanol

78 °C

Ethanoic acid

118 °C

Density

Ethanol

0.8 g/cm³

Ethanoic acid

1.1 g/cm³

Flammable?

Ethanol

Yes

Ethanoic acid

Yes

WHAT YOU'VE LEARNED

A quick recap of today's lesson.

Capital letters tell you which atoms. Small numbers tell you how many. Change one small number and it's no longer the same substance.

What you need to know

  • A chemical symbol is one or two letters that stand for an element, and the first letter is always a capital: Na is sodium, K is potassium, Br is bromine.
  • A chemical formula shows which types of atom a substance contains, and either the number or the ratio of atoms of each.
  • An element contains only one type of atom. N₂ is two nitrogen atoms bonded together; O₂ is two oxygen atoms joined together.
  • A compound is two or more elements chemically joined (bonded), so it contains two or more different types of atom — for example CO, HCl and H₂O.
  • A subscript counts only the atom whose symbol it follows, and a symbol with no subscript means one atom: write NO, not N₁O₁.
  • Subscripts are written small and just below the line (C₂H₆, not C²H⁶). Raised numbers are used in maths for squaring, not in formulae.
  • In a giant structure the formula gives a ratio: NaCl means one chlorine atom for every sodium atom.
  • Compounds can contain the same elements in different ratios and still be different substances with different properties — like water (H₂O) and hydrogen peroxide (H₂O₂).

The big picture

A chemical formula tells you what a substance is made of. The symbols say which types of atom are there; each small number (subscript) counts only the atom just before it, and no number means one atom. One type of atom makes an element, like N₂; two or more types bonded together make a compound, like H₂O. For a giant structure such as NaCl, the formula gives a ratio of atoms rather than a count. The same elements in a different ratio make a different compound with different properties.

Key points

1Capital letters start symbols, so count the capitals to find the elements.
2A subscript belongs to the symbol just before it — and no subscript means one.
3One type of atom = element. Two or more types bonded together = compound.
4Counting atoms gives the ratio: two hydrogen to one sulfur is 2:1; one copper, one sulfur, four oxygen is 1:1:4.
5Same elements in a different ratio make a different compound with different properties.

Worked example

Problem

A molecule of ammonia is made of one nitrogen atom and three hydrogen atoms. Write the formula for ammonia, then say whether ammonia is an element or a compound.

⚠ Watch out

Letting a subscript count the wrong atoms. In CO₂ the 2 counts only the oxygen — it does not double the carbon, and it does not double the whole formula. Read each number with the one symbol just before it.

🧠

Memory hook

Capitals name the atoms; the little number underneath counts the one in front. No number? Just one.

✓

Check yourself

Look at N₂O. Which elements does it contain, how many atoms of each, and is it an element or a compound? Say the ratio of nitrogen to oxygen out loud before you check.

Flashcards

(14)
What is a chemical symbol?
One or two letters that stand for an element. The first letter is always a capital, e.g. K or Na.
Which elements are Na, K and Br?
Na is sodium, K is potassium and Br is bromine.
What does a chemical formula tell you?
Which types of atom a substance contains, and the number or ratio of atoms of each.
What makes a substance an element?
It contains only one type of atom — like N₂, two nitrogen atoms bonded together.
What makes a substance a compound?
Two or more elements chemically joined (bonded), so it has two or more different types of atom.
Which atoms does a subscript count?
Only the atoms of the element whose symbol it comes straight after.
A symbol in a formula has no number after it. How many of that atom are there?
One. You never write a 1 — it's NO, not N₁O₁.
Where do the numbers in a formula go?
Small and just below the line (C₂H₆). Raised numbers are for squaring in maths, so C²H⁶ is wrong.
What does NaCl tell you about sodium chloride?
It forms a giant structure with one chlorine atom for every sodium atom — a 1:1 ratio, not one tiny pair.
How do you turn atom counts into a ratio?
Write the counts in order with colons: two hydrogen to one sulfur is 2:1; three carbon for every eight hydrogen is 3:8.
Copper sulfate contains one copper, one sulfur and four oxygen. How many elements, and what ratio?
Three elements, in a 1:1:4 ratio of copper to sulfur to oxygen.
H₂O and H₂O₂: same substance or not?
Different compounds. Same elements, different ratio — water is safe to drink, hydrogen peroxide is very corrosive and harmful.
Name three different compounds made from just nitrogen and oxygen.
NO, NO₂ and N₂O₄ — the same two elements bonded in different numbers.
Ethanol is C₂H₆O and ethanoic acid is C₂H₄O₂. How do their properties compare?
Ethanol boils at 78 °C (density 0.8 g/cm³); ethanoic acid boils at 118 °C (density 1.1 g/cm³). Both are flammable.

Tap any card to flip it, or use Study as deck to go through them one at a time. In the full lesson these run as a spaced-repetition deck — you rate each card Hard, Good or Easy and the tricky ones keep coming back until they stick.

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